Abstract: Chloride-induced corrosion (CIC) is a primary reason of deterioration in reinforced concrete (RC), particularly in marine structures which causes cracking, degradation, and decreased service life. Advances in the 4th Industrial Revolution have enabled utilization of machine learning techniques in different fields of civil engineering. This study develops an Artificial Neural Network (ANN) enhanced by Particle Swarm Optimization (PSO) to predict rebar corrosion in polypropylene fiber reinforced concrete (PFRC). Accelerated corrosion tests were performed using the impressed current method on samples with varying polypropylene fiber content, concrete cover (CC), and bar diameter (BD). Experimental results showed that the 3-7-1 network structure (NS) (3 input neurons (IN), 7 hidden neurons (HN), 1 output neuron (ON)) achieved the highest accuracy with correlation coefficient (R) of 0.98969, mean squared error (MSE) of 0.18846, and mean absolute percentage error (MAPE) of 7.832 %. Employing the generated connection weights (CW) from the governing model (GM), through Olden's connection weights approach, observed that the concrete cover had the most significant influence on corrosion (-43.231%), followed by bar diameter (33.717%) and fiber content (-23.052%). It highlights that increasing concrete cover and fiber content significantly reduces corrosion in PFRC, which may be used by civil engineering professionals as it offers insights for enhancing the durability of reinforced concrete structures. This approach supports SDG 9 (Sustainable Development Goal 9: Industry, Innovation, and Infrastructure) by promoting resilient, innovative construction methods and contributes to SDG 11 (Sustainable Development Goal 11: Sustainable Cities and Communities) by enhancing the longevity and sustainability of urban infrastructure.